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Generalized Helmholtz theorem : ウィキペディア英語版
Generalized Helmholtz theorem
The generalized Helmholtz theorem on skates is the multi-dimensional generalization of the Helmholtz theorem which is valid only in one dimension. The generalized Helmholtz theorem reads as follows.
Let
:\mathbf=(p_1,p_2,...,p_s),
:\mathbf=(q_1,q_2,...,q_s),
be the canonical coordinates of a ''s''-dimensional Hamiltonian system, and let
: H(\mathbf,\mathbf;V)=K(\mathbf)+\varphi(\mathbf;V)
be the Hamiltonian function, where
:K=\sum_^\frac,
is the kinetic energy and
:\varphi(\mathbf;V)
is the potential energy which depends on a parameter V.
Let the hyper-surfaces of constant energy in the 2''s''-dimensional phase space of the system be metrically indecomposable and let \left\langle \cdot \right\rangle_t denote time average. Define the quantities E, P, T, S, as follows:
:E = K + \varphi ,
:T = \frac\left\langle K\right\rangle _,
:P = \left\langle -\frac\right\rangle _,
:S(E,V) = \log \int_;V) \leq E} d^s\mathbfd^s \mathbf.
Then:
:dS = \frac.
== Remarks ==
The thesis of this theorem of classical mechanics reads exactly as the heat theorem of thermodynamics. This fact shows that thermodynamic-like relations exist between certain mechanical quantities in multidimensional ergodic systems. This in turn allows to define the "thermodynamic state" of a multi-dimensional ergodic mechanical system, without the requirement that the system be composed of a large number of degrees of freedom. In particular the temperature T is given by twice the time average of the kinetic energy per degree of freedom, and the entropy S by the logarithm of the phase space volume enclosed by the constant energy surface (i.e. the so-called volume entropy).

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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